Synthesis, Spectroscopy and Electrochemistry of nitroso terpyridine-{1-(alkyl)-2-(arylazo) imidazole}ruthenium(II) Complexes
| Dublin Core | PKP Metadata Items | Metadata for this Document | |
| 1. | Title | Title of document | Synthesis, Spectroscopy and Electrochemistry of nitroso terpyridine-{1-(alkyl)-2-(arylazo) imidazole}ruthenium(II) Complexes |
| 2. | Creator | Author's name, affiliation, country | Prithwiraj Byabartta; Departmento de Quimica Inorganica-Instituto de Ciencia deMateriales de Aragon, Universidad de Zaragoza-CSIC, Zaragoza-50009; Spain |
| 3. | Subject | Discipline(s) | |
| 3. | Subject | Keyword(s) | 1-(alkyl)-2-(arylazo)imidazole; nitro; nitroso, ruthenium; amines; MLCT; NMR; CV; IR; reactivity |
| 4. | Description | Abstract | Silver assisted aquation of blue [RuCl(tpy)(RaaiR´)](ClO4) (1a-1i) leads to the synthesis of solvento species, blue-violet [Ru(OH2)(tpy)(RaaiR´)](ClO4)(2a-2i), [RaaiR´ =p-R-C6H5-N=N-C3H2-NN, abbreviated as N,N/-chelator, R = Me, Et, Bz, p-R=H Me, Cl] that have been reacted with NaNO2in warm EtOH resulting in violet nitro complexes of the type, [Ru(NO2)(tpy)(RaaiR)](ClO4)(3a-3i). The nitrite complexes are useful synthons of electrophilic nitrosyls, and on triturating the nitro compounds with conc. HClO4 nitrosyl derivatives, [Ru(NO)(tpy)(RaaiR)](ClO4)3 are isolated. The diazotization of the primary aromatic amines with a strongly electrophilic mononitrosyl complex in acetonotrile and dichloromethane solution was thoroughly studied. |
| 5. | Publisher | Organizing agency, location | World science and research publishing |
| 6. | Contributor | Sponsor(s) | |
| 7. | Date | (YYYY-MM-DD) | 2014-10-05 |
| 8. | Type | Status & genre | Peer-reviewed Article |
| 8. | Type | Type | |
| 9. | Format | File format | PDF, XML |
| 10. | Identifier | Uniform Resource Identifier | http://www.journals.wsrpublishing.com/index.php/tjasr/article/view/9 |
| 11. | Source | Title; vol., no. (year) | The Journal of Applied Sciences Research; Vol 1, No 1 (2014) |
| 12. | Language | English=en | en |
| 13. | Relation | Supp. Files | |
| 14. | Coverage | Geo-spatial location, chronological period, research sample (gender, age, etc.) | |
| 15. | Rights | Copyright and permissions |
Copyright (c) 2014 The Journal of Applied Sciences Research This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License. |